Bidentate cycloimidate palladium complexes with aliphatic and aromatic anagostic bonds

Stephan Schölera, Meike H. Wahla, Nicole I. C. Wurstera, Arik Pulsa, Christof Hättigb, and Gerald Dykerb

a Ruhr-Universität Bochum, 44801 Faculty of Chemistry, Organic Chemistry II Universitätsstr. 150, 44781 Bochum, Germany
b Lehrstuhl für Theoretische Chemie, Ruhr-Universität Bochum, D-44801 Bochum, Germany

Chem. Commun. 50, 5909-5911 (2014)
(Received 10th February 2014; Accepted 6th April 2014; First published on the web 8th April 2014)

Palladium(II) complexes of bidentate cycloimidate ligand systems with a triarylmethyl moiety exhibit exceptional downfield shifts in proton NMR spectra due to rare anagostic interactions.

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